Pincer Metal Complexes

Pincer Metal Complexes
Author: Akshai Kumar
Publsiher: Elsevier
Total Pages: 244
Release: 2021-11-12
ISBN: 0128220929
Category: Science
Language: EN, FR, DE, ES & NL

Pincer Metal Complexes Book Excerpt:

Pincer-Metal Complexes: Applications in Catalytic Dehydrogenation Chemistry provides an overview of pincer-metal catalytic systems that transform hydrocarbons and their derivatives from an synthetic and mechanistic point-of-view. This book provides thorough coverage of the operating mechanisms and dehydrogenation catalyst compatibility in both functionalized and unfunctionalized hydrocarbon systems. In addition, it includes success stories of pincer-metal systems, as well as current and future challenges. The book is an ideal reference for researchers practicing synthetic organic chemistry, inorganic chemistry, organometallic chemistry and catalysis in academia and industry. In recent years there has been a surge in the research on hydrocarbon dehydrogenation catalytic systems that are compatible with polar substituents. This helps facilitate formulation of tandem processes that are not limited to hydrocarbon transformation but also to hydrocarbon functionalization in a single pot. Covers applications of pincer-metal complexes in organic transformations Includes pincer-group 8 and 9 metal complexes for alkane dehydrogenations Features a discussion of pincer-metal complexes for the dehydrogenation of functionalized hydrocarbons and electro-catalytic transformations

The Privileged Pincer Metal Platform Coordination Chemistry Applications

The Privileged Pincer Metal Platform  Coordination Chemistry   Applications
Author: Gerard van Koten,Robert A Gossage
Publsiher: Springer
Total Pages: 374
Release: 2015-08-27
ISBN: 3319229273
Category: Science
Language: EN, FR, DE, ES & NL

The Privileged Pincer Metal Platform Coordination Chemistry Applications Book Excerpt:

The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics in pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors.

Pincer Compounds

Pincer Compounds
Author: David Morales-Morales
Publsiher: Elsevier
Total Pages: 754
Release: 2018-04-11
ISBN: 0128129328
Category: Science
Language: EN, FR, DE, ES & NL

Pincer Compounds Book Excerpt:

Pincer Compounds: Chemistry and Applications offers valuable state-of-the-art coverage highlighting highly active areas of research—from mechanistic work to synthesis and characterization. The book focuses on small molecule activation chemistry (particularly H2 and hydrogenation), earth abundant metals (such as Fe), actinides, carbene-pincers, chiral catalysis, and alternative solvent usage. The book covers the current state of the field, featuring chapters from renowned contributors, covering four continents and ranging from still-active pioneers to new names emerging as creative strong contributors to this fascinating and promising area. Over a decade since the publication of Morales-Morales and Jensen’s The Chemistry of Pincer Compounds (Elsevier 2007), research in this unique area has flourished, finding a plethora of applications in almost every single branch of chemistry—from their traditional application as very robust and active catalysts all the way to potential biological and pharmaceutical applications. Describes the chemistry and applications of this important class of organometallic and coordination compounds Includes contributions from global leaders in the field, featuring pioneers in the area as well as emerging experts conducting exciting research on pincer complexes Highlights areas of promising and active research, including small molecule activation, earth abundant metals, and actinide chemistry

Organometallic Pincer Chemistry

Organometallic Pincer Chemistry
Author: Gerard van Koten,David Milstein
Publsiher: Springer
Total Pages: 356
Release: 2012-09-17
ISBN: 3642310818
Category: Science
Language: EN, FR, DE, ES & NL

Organometallic Pincer Chemistry Book Excerpt:

Gerard van Koten: The Mono-anionic ECE-Pincer Ligand - a Versatile Privileged Ligand Platform: General Considerations.- Elena Poverenov, David Milstein: Non-Innocent Behavior of PCP and PCN Pincer Ligands of Late Metal Complexes.- Dean M. Roddick: Tuning of PCP Pincer Ligand Electronic and Steric Properties.- Gemma R. Freeman, J. A. Gareth Williams: Metal Complexes of Pincer Ligands: Excited States, Photochemistry, and Luminescence.- Davit Zargarian, Annie Castonguay, Denis M. Spasyuk: ECE-Type Pincer Complexes of Nickel.- Roman Jambor and Libor Dostál: The Chemistry of Pincer Complexes of 13 - 15 Main Group Elements.- Kálmán J. Szabo: Pincer Complexes as Catalysts in Organic Chemistry.- Jun-ichi Ito and Hisao Nishiyama: Optically Active Bis(oxazolinyl)phenyl Metal Complexes as Multi-potent Catalysts.- Anthony St. John, Karen I. Goldberg, and D. Michael Heinekey: Pincer Complexes as Catalysts for Amine Borane Dehydrogenation.- Dmitri Gelman and Ronit Romm: PC(sp3)P Transition Metal Pincer Complexes: Properties and Catalytic Applications.- Jennifer Hawk and Steve Craig: Physical Applications of Pincer Complexes.

Advances in Organometallic Chemistry

Advances in Organometallic Chemistry
Author: Pedro J. Perez
Publsiher: Academic Press
Total Pages: 314
Release: 2020-03-03
ISBN: 0128206918
Category: Science
Language: EN, FR, DE, ES & NL

Advances in Organometallic Chemistry Book Excerpt:

Advances in Organometallic Chemistry, Volume 73, the latest release in this longstanding serial, is known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more. It is ideal for a wide range of researchers involved in organometallic chemistry, including synthetic protocols, mechanistic studies and practical applications. Specific chapters in this new release include Metal carbonyl promoted multicomponent coupling of alkyne for synthesis of heterocyclic compounds, Group 10 metal(0) complexes stabilized by phosphorus and carbon donor ligands, Synthesis of Nitrogen-containing Molecules via Transition Metal-Catalyzed Reactions on Isoxazoles, Anthraniils and Benzoisoxazoles, and more. Contains contributions from leading authorities in the field of organometallic chemistry Covers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more Informs and updates readers on the latest developments in the field Carefully edited to provide easy-to-read material

Pincer and Pincer Type Complexes

Pincer and Pincer Type Complexes
Author: Kálmán J. Szabó,Ola F. Wendt
Publsiher: John Wiley & Sons
Total Pages: 320
Release: 2014-06-10
ISBN: 3527681337
Category: Science
Language: EN, FR, DE, ES & NL

Pincer and Pincer Type Complexes Book Excerpt:

This new book on this hot topic summarizes the key achievements for the synthesis and catalytic applications of pincer and pincer-type complexes, providing readers with the latest research highlights. The editors have assembled an international team of leaders in the field, and their contributions focus on the application of various pincer complexes in modern organic synthesis and catalysis, such as C-C and C-X bond forming reactions, C-H bond functionalization, and the activation of small molecules, as well as asymmetric catalysis. A must-have for every synthetic chemist in both academia and industry intending to develop new catalysts and improved synthetic protocols.

The Chemistry of Pincer Compounds

The Chemistry of Pincer Compounds
Author: David Morales-Morales,Craig G.M. Jensen
Publsiher: Elsevier
Total Pages: 466
Release: 2011-08-11
ISBN: 9780080545158
Category: Science
Language: EN, FR, DE, ES & NL

The Chemistry of Pincer Compounds Book Excerpt:

Pincer complexes are formed by the binding of a chemical structure to a metal atom with at least one carbon-metal bond. Usually the metal atom has three bonds to a chemical backbone, enclosing the atom like a pincer. The resulting structure protects the metal atom and gives it unique properties. The last decade has witnessed the continuous growth in the development of pincer complexes. These species have passed from being curiosity compounds to chemical chameleons able to perform a wide variety of applications. Their unique metal bound structures provide some of the most active catalysts yet known for organic transformations involving the activation of bonds. The Chemistry of Pincer Compounds details use of pincer compounds including homogeneous catalysis, enantioselective organic transformations, the activation of strong bonds, the biological importance of pincer compounds as potential therapeutic or pharmaceutical agents, dendrimeric and supported materials. * Describes the chemistry and applications of this important class of organometallic and coordination compounds * Covers the areas in which pincer complexes have had an impact * Includes information on more recent and interesting pincer compounds not just those that are well-known

Advances in Bioorganometallic Chemistry

Advances in Bioorganometallic Chemistry
Author: Toshikazu Hirao,Toshiyuki Moriuchi
Publsiher: Elsevier
Total Pages: 472
Release: 2018-11-30
ISBN: 0128141980
Category: Science
Language: EN, FR, DE, ES & NL

Advances in Bioorganometallic Chemistry Book Excerpt:

Advances in Bioorganometallic Chemistry examines the synthesis, structure and reactivity of bioorganometallics, their pharmaceutical applications, hydrogenase, vitamin B12-like systems, and metalloproteins. It is written by the top researchers in the field and compiled by editors Toshikazu Hirao and Toshiyuki Moriuchi. Developments in this new field of bioorganometallic chemistry, a hybrid between biology and organometallic chemistry, happen very quickly and this comprehensive reference offers the latest research and findings in the field. The book features a discussion of the synthesis, structure, and reactivity of bioorganometallics, and an examination of hydrogenase-like systems, which were designed to demonstrate catalytic activities and functional properties. Advances in Bioorganometallic Chemistry also includes a discussion of bioorganometallics as they relate to medicinal chemistry, specifically applications of metalloproteins, metalloenzymes, and applications in bioimaging. The book concludes with coverage of vitamin B12-like systems, including the latest developments in derivatives designed to perform bio-inspired catalytic reactions. This work is a valuable resource for chemists working in organometallic chemistry and biology, including biochemists, bioorganic chemists, bioinorganic chemists, as well as pharmaceutical scientists, medicinal chemists, and students studying in these areas. Representative authors: R. H. Fish, T. Moriuchi, T. Hirao, H.-B. Kraatz, H. Takaya, T. P. Curran, G. van Koten. E. Rosenberg, J. M. Lynam, C. G. Hartinger, U. Schatzschneider, G. S. Smith, R. Alberto, S. Takenaka, T. Ihara, T. Hayashi, T. Ueno, P. Schollhammer, Y. Shomura, Y. Hisaeda, H. Shimakoshi, B. Kräutler Provides a balanced overview of the latest research in the field of bioorganometallic chemistry, drawing together the top researchers from around the world Covers topics in the areas of synthesis, reactivity, hydrogenase-like systems, medicinal chemistry, applications of metalloproteins, metalloenzymes, and applications in bioimaging

Palladacycles

Palladacycles
Author: Jairton Dupont,Michel Pfeffer
Publsiher: John Wiley & Sons
Total Pages: 433
Release: 2008-10-13
ISBN: 3527317813
Category: Science
Language: EN, FR, DE, ES & NL

Palladacycles Book Excerpt:

From synthesis to applications in catalysis, material science and biology this much-needed book is the first to comprehensively present everything you need to know about palladacycles. Renowned international authors guarantee high-quality content, making this a must-have for everyone working in the field.

Metal Ligand Co operativity

Metal Ligand Co operativity
Author: Gerard van Koten,Karl Kirchner,Marc-Etienne Moret
Publsiher: Springer Nature
Total Pages: 451
Release: 2021-03-29
ISBN: 3030689166
Category: Science
Language: EN, FR, DE, ES & NL

Metal Ligand Co operativity Book Excerpt:

This book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of significant recent developments in the area of metal-ligand cooperativity, with a focus on pincer architectures. The various contributions highlight the widespread impact of M–L co-operativity phenomena on modern organometallic chemistry and catalyst development. The development of efficient and selective catalytic transformations relies on the understanding and fine control of the various elementary reactions that constitutes a catalytic cycle. Co-operative ligands, which actively participate in bond making and bond breaking together to the metal they support, open up new avenues in this area. In particular, buttressing a weak or reactive metal-ligand bond by flanking coordinating arms in a pincer ligand design is proving a versatile strategy to access robust metal complexes that exhibit unusual and selective reactivity patterns.

Recent Progress in Computational Sciences and Engineering 2 vols

Recent Progress in Computational Sciences and Engineering  2 vols
Author: Theodore Simos
Publsiher: CRC Press
Total Pages: 1600
Release: 2019-05-07
ISBN: 1466564512
Category: Computers
Language: EN, FR, DE, ES & NL

Recent Progress in Computational Sciences and Engineering 2 vols Book Excerpt:

This volume brings together selected contributed papers presented at the International Conference of Computational Methods in Science and Engineering (ICCMSE 2006), held in Chania, Greece, October 2006. The conference aims to bring together computational scientists from several disciplines in order to share methods and ideas. The ICCMSE is unique in its kind. It regroups original contributions from all fields of the traditional Sciences, Mathematics, Physics, Chemistry, Biology, Medicine and all branches of Engineering. It would be perhaps more appropriate to define the ICCMSE as a conference on computational science and its applications to science and engineering. Topics of general interest are: Computational Mathematics, Theoretical Physics and Theoretical Chemistry. Computational Engineering and Mechanics, Computational Biology and Medicine, Computational Geosciences and Meteorology, Computational Economics and Finance, Scientific Computation. High Performance Computing, Parallel and Distributed Computing, Visualization, Problem Solving Environments, Numerical Algorithms, Modelling and Simulation of Complex System, Web-based Simulation and Computing, Grid-based Simulation and Computing, Fuzzy Logic, Hybrid Computational Methods, Data Mining, Information Retrieval and Virtual Reality, Reliable Computing, Image Processing, Computational Science and Education etc. More than 800 extended abstracts have been submitted for consideration for presentation in ICCMSE 2005. From these 500 have been selected after international peer review by at least two independent reviewers.

Organic Materials as Smart Nanocarriers for Drug Delivery

Organic Materials as Smart Nanocarriers for Drug Delivery
Author: Alexandru Mihai Grumezescu
Publsiher: William Andrew
Total Pages: 768
Release: 2018-03-26
ISBN: 0128136642
Category: Science
Language: EN, FR, DE, ES & NL

Organic Materials as Smart Nanocarriers for Drug Delivery Book Excerpt:

Organic Materials as Smart Nanocarriers for Drug Delivery presents the latest developments in the area of organic frameworks used in pharmaceutical nanotechnology. An up-to-date overview of organic smart nanocarriers is explored, along with the different types of nanocarriers, including polymeric micelles, cyclodextrins, hydrogels, lipid nanoparticles and nanoemlusions. Written by a diverse range of international academics, this book is a valuable reference for researchers in biomaterials, the pharmaceutical industry, and those who want to learn more about the current applications of organic smart nanocarriers. Explores the most recent molecular- and structure-based applications of organic smart nanocarriers in drug delivery Highlights different smart nanocarriers and assesses their intricate organic structural properties for improving drug delivery Assesses how molecular organic frameworks lead to more effective drug delivery systems

Computational Chemistry

Computational Chemistry
Author: Anonim
Publsiher: Academic Press
Total Pages: 558
Release: 2019-02-20
ISBN: 0128157291
Category: Science
Language: EN, FR, DE, ES & NL

Computational Chemistry Book Excerpt:

Computational Chemistry, Volume 73, the latest release in the Advances in Inorganic Chemistry series, presents timely and informative summaries on current progress in a variety of subject areas. This acclaimed serial features reviews written by experts in the field, serving as an indispensable reference to advanced researchers that empowers readers to pursue new developments in each field. Users will find this to be a comprehensive overview of recent findings and trends from the last decade that covers various kinds of inorganic topics, from theoretical oriented supramolecular chemistry, to the quest for accurate calculations of spin states in transition metals. Features comprehensive reviews on the latest developments in computational studies in inorganic chemistry Includes contributions from leading experts in the field of inorganic reaction mechanisms Serves as an indispensable reference to advanced researchers in many related fields

Comprehensive Organic Synthesis

Comprehensive Organic Synthesis
Author: Anonim
Publsiher: Newnes
Total Pages: 9806
Release: 2014-02-14
ISBN: 008097743X
Category: Science
Language: EN, FR, DE, ES & NL

Comprehensive Organic Synthesis Book Excerpt:

The second edition of Comprehensive Organic Synthesis—winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers—builds upon the highly respected first edition in drawing together the new common themes that underlie the many disparate areas of organic chemistry. These themes support effective and efficient synthetic strategies, thus providing a comprehensive overview of this important discipline. Fully revised and updated, this new set forms an essential reference work for all those seeking information on the solution of synthetic problems, whether they are experienced practitioners or chemists whose major interests lie outside organic synthesis. In addition, synthetic chemists requiring the essential facts in new areas, as well as students completely new to the field, will find Comprehensive Organic Synthesis, Second Edition an invaluable source, providing an authoritative overview of core concepts. Winner of the 2015 PROSE Award for Multivolume Reference/Science from the Association of American Publishers Contains more than170 articles across nine volumes, including detailed analysis of core topics such as bonds, oxidation, and reduction Includes more than10,000 schemes and images Fully revised and updated; important growth areas—including combinatorial chemistry, new technological, industrial, and green chemistry developments—are covered extensively

Metal Complexes Containing Boron Based Ligands

Metal Complexes Containing Boron Based Ligands
Author: Gareth Owen
Publsiher: MDPI
Total Pages: 110
Release: 2019-10-30
ISBN: 3039215841
Category: Science
Language: EN, FR, DE, ES & NL

Metal Complexes Containing Boron Based Ligands Book Excerpt:

Boron-based compounds have been utilized as ligands within transition metal complexes for many decades. The diversity of such compounds in terms of varying functional groups is truly exceptional. Boron compounds are of high interest due to the great potential to modify the substituents around the boron center and to produce a broad range of structural motifs. The many different ways these compounds can coordinate or interact with transition metal centers is astonishing. Examples of transition metal complexes containing boron-based ligands include scorpionates, cluster-type borane- and carboranes, borates, and phosphine-stabilized borylene ligands. This Special Issue brings together a collection of articles focusing on recent developments in the aforementioned boron-based ligands. The articles reported in this book will provide the reader with an overview of the types of boron-based ligands which are currently being researched in groups around the world.

Copper I Chemistry of Phosphines Functionalized Phosphines and Phosphorus Heterocycles

Copper I  Chemistry of Phosphines  Functionalized Phosphines and Phosphorus Heterocycles
Author: Maravanji S. Balakrishna
Publsiher: Elsevier
Total Pages: 442
Release: 2019-04-25
ISBN: 0128156945
Category: Science
Language: EN, FR, DE, ES & NL

Copper I Chemistry of Phosphines Functionalized Phosphines and Phosphorus Heterocycles Book Excerpt:

Copper(I) Complexes of Phosphines, Functionalized Phosphines and Phosphorus Heterocycles is a comprehensive guide to one of the most widely used and extensively studied metals: copper. The numerous practical applications of copper compounds are discussed, including homogeneous and heterogeneous catalysis and their use as fungicides, pesticides, pigments for paints, resins and glasses, and in high-temperature superconductors. The remarkable structural flexibility of simple copper(I) complexes, such as cuprous halides is covered, including numerous structural motifs that, when combined with different ligand systems, exhibit linear, trigonal planar or tetrahedral geometries. This work is an essential reference for inorganic and coordination chemists, as well as researchers working on catalysis, anticancer reagents, luminescence, fluorescence and photophysical aspects. Discusses the properties of copper and similarities to noble metals, such as their corrosion resistance, high thermal and electrical conductivity and rich coordination chemistry Includes the copper(I) coordination chemistry of tertiary phosphines, bisphosphines and phosphines containing other donor atoms and their potential application in catalysis, biosystems and photochemical areas Features a discussion of the rich photochemistry exhibited by some mixed-ligand copper(I) complexes (phosphines with heteroaromatic ligands) which can exhibit coprophilic interactions, photoluminescence and thermochromic properties

Organometallic Chemistry Research Perspectives

Organometallic Chemistry Research Perspectives
Author: Richard P. Irwin
Publsiher: Nova Publishers
Total Pages: 324
Release: 2007
ISBN: 9781600217807
Category: Science
Language: EN, FR, DE, ES & NL

Organometallic Chemistry Research Perspectives Book Excerpt:

Organometallic chemistry is based on the reactions and use of a class of compounds (R-M) that contain a covalent bond between carbon and metal. They are prepared either by direct reaction of the metal with an organic compound or by replacement of a metal from another organometallic substance. This book presents research in this field.

Cooperative Catalysis

Cooperative Catalysis
Author: René Peters
Publsiher: John Wiley & Sons
Total Pages: 456
Release: 2015-01-30
ISBN: 3527681043
Category: Technology & Engineering
Language: EN, FR, DE, ES & NL

Cooperative Catalysis Book Excerpt:

Written by experts in the field, this is a much-needed overview of the rapidly emerging field of cooperative catalysis. The authors focus on the design and development of novel high-performance catalysts for applications in organic synthesis (particularly asymmetric synthesis), covering a broad range of topics, from the latest progress in Lewis acid / Brønsted base catalysis to e.g. metal-assisted organo catalysis, cooperative metal/enzyme catalysis, and cooperative catalysis in polymerization reactions and on solid surfaces. The chapters are classified according to the type of cooperating activating groups, and describe in detail the different strategies of cooperative activation, highlighting their respective advantages and pitfalls. As a result, readers will learn about the different concepts of cooperative catalysis, their corresponding modes of operation and their applications, thus helping to find a solution to a specific synthetic catalysis problem.

Chemistry of Polymeric Metal Chelates

Chemistry of Polymeric Metal Chelates
Author: Gulzhian I. Dzhardimalieva,Igor E. Uflyand
Publsiher: Springer
Total Pages: 1020
Release: 2018-02-13
ISBN: 3319560247
Category: Technology & Engineering
Language: EN, FR, DE, ES & NL

Chemistry of Polymeric Metal Chelates Book Excerpt:

This book deals with the chemistry of polymeric metal chelates. The main results and the production and chemical structure of polymers with chelate units as well as the specificity of metal complex binding of different structure are presented here. This book also reveals the transformations which components undergo in the course of chelation. Special attention is paid not only to synthetic but also to natural (including living) systems. The usage of polymeric metal chelates and their development are examined. The related research was performed for chelates with chain structure. This book is useful to researchers being active in synthesis and design of macromolecular metal chelates

Chemistry of Thioamides

Chemistry of Thioamides
Author: Toshiaki Murai
Publsiher: Springer
Total Pages: 238
Release: 2019-05-14
ISBN: 9811378282
Category: Science
Language: EN, FR, DE, ES & NL

Chemistry of Thioamides Book Excerpt:

This book covers whole aspects of the sulfur isologues of amides. Starting from the synthetic methods of thioamides, a range of synthetic applications to the construction of carbon–sulfur and carbon–carbon bonds, to asymmetric reactions, to formation of heterocycles are described. Among the array of thiocarbonyl compounds, thioamides are readily handled in room temperature air. Some of their characteristic features are that the polarity of C=S bonds in thioamides is much smaller than C=O bonds in ordinary amides, that thioamides possess higher HOMO and lower LUMO when compared with those of ordinary amides, and that carbon atoms alpha to the C=S and nitrogen atoms in thioamides are more acidic than those in ordinary amides. Theoretical studies further disclose their features. Thioamides are also used as ligands to a wide variety of metals. Their unique photophysical properties and catalytic activities are described here. Characteristic features of biologically relevant thioamides, e.g., thiopeptides and related compounds, are the final focus of the book.